To provide the basic information for the water quality management of the Sumjin River Basin, delivery ratios for flow duration were studied. Using the day-interval data set of discharge and water quality observed from the Chooryeong-cheon watershed, the flow-duration and discharge-load relation curves for the watershed were established, then the load-duration curve was constructed. Delivery ratios for flow duration were also developed. Delivery ratios showed wide variation according to flow conditions. In general, delivery ratio of high flow condition showed higher value reflecting nonpoint source pollution contribution from the forest dominating watershed. To resolve this problem, a regression model explaining the relation between flow rate and delivery ratio was suggested. The delivery ratios for different flow regime could be used for pollutant load estimation and TMDL (Total maximum daily load) development.