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논문 리스트

2014
아임계수를 이용한 토양 내 벤조[a]피렌 정화 .
한국지하수토양환경학회
박정훈
논문정보
Publisher
지하수토양환경
Issue Date
2014-12-01
Keywords
-
Citation
-
Source
-
Journal Title
-
Volume
19
Number
6
Start Page
13
End Page
17
DOI
ISSN
15986438
Abstract
Subcritical water acts like an organic solvent at elevated temperature in terms of its physicochemical properties. Takinginto account this advantage, the remediation experiments of benzo[a]pyrene contaminated soil (8.45 mg/kg of initialconcentration) were conducted using subcritical water extraction apparatus. The effect of operating factors on the removalefficiency was studied at the varying the conditions of the water temperature ranging 200~300oC, extraction time 30~90min, and flow rate 0.3~2.0 mL/min. 12 g of benzo[a]pyrene contaminated soil was inserted into the extraction cell andplaced into the reactor and then the subcritical water was driven through the cell. In this study, the removal efficiency ofbenzo[a]pyrene was increased from 55.1 to 98.1% when the temperature increased from 200 to 300oC. The removalefficiency was decreased from 97.0 to 77.0% when the flow rate increased from 0.3 to 2.0 mL/min, suggesting that theextraction is limited by intra-particle diffusion. The 30 min reaction time was determined as an effective treatment time at250oC. Based on the results, the optimum condition for the remediation of benzo[a]pyrene contaminated soil wassuggested to be 250oC, 30 min, and 0.3 mL/min.

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이름 소속
박정훈 환경에너지공학과