Affective computing has gained increasing interest in the recent years with the development of potential applications in Human computer interaction (HCI) and healthcare. Although momentous research has been done on human emotion recognition, however, in comparison to speech and facial expression less attention has been paid to physiological signals. In this paper, Electroencephalogram (EEG) signals from different brain regions were investigated using modified wavelet energy features. For minimization of redundancy and maximization of relevancy among features, mRMR algorithm was deployed significantly. EEG recordings of a publically available “DEAP” database have been used to classify four classes of emotions with Multi class Support Vector Machine. The proposed approach shows significant performance compared to existing algorithms.