In this study, several concrete-block blast tests and AUTODYN numerical analyses were conducted to analyze the effects of different stemming and coupling materials on explosion results. Air, sand, and polymer gel were used as both the stemming and coupling materials. The stemming and coupling effects of these materials were compared with those of the full-charge condition. Soil-covered or buried concrete blocks were used for field crater tests. It was found from the concrete block tests and numerical analyses that both the crater size and the peak pressure around the blast hole were higher when the polymer gel was used than when the sand and the decoupling condition were used. The numerical analyses revealed the same trend as those of the field tests. Pressure peaks in concrete block models were calculated to be 37, 30, and 16 MPa, respectively, for the cases of the polymer gel, sand, and no stemming and decoupling condition. The pressure peak was 52 MPa in the case of full-charge condition, which was the highest pressure. But the damage area for the case was smaller than that obtained from the use of polymer gel. Full-charge was also used as a reference test.