This paper is presented an experimental study of flow boiling heat transfer characteristics of ammonia, and is focused on pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal small tube with inner diameter of 3.0mm and length of 2000mm. The direct heating method is applied for supplying heat to the refrigerant, where the test tube is uniformly heated by electric current. The local heat transfer coefficients were obtained over a heat flux range of 20 to 80 kW/㎡, a mass flux range of 50 to 500 kg/㎡s, a saturation temperature range of 0 to 10°C, and quality up to 1.0. The pressure drops increase with increasing mass flux and heat flux, and with decreasing saturation temperature. The heat transfer coefficients increase with increasing mass flux and saturation temperature in middle and high quality region. And the local heat transfer coefficient increase with increasing heat flux in low quality region. The heat transfer coefficient of the experimental result was compared with six existing heat transfer coefficient correlation. A new boiling heat transfer coefficient correlation based on the superposition model for ammonia in small tubes is developed average deviation of -0.17% and mean deviation of 10.85%.